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Total Alkalinity (Buffering Capacity) (KH,
Alkalinity) refers to waters ability to keep the pH stable as acids
or bases are added. pH buffering capacity are intertwined with one another;
although one might think that adding equal volumes of an acid and neutral
water would result in a pH halfway in between, this rarely happens in
practice. If the water has sufficient buffering capacity, the buffering
capacity can absorb and neutralize the added acid without significantly
changing the pH level. Conceptually, a buffer acts somewhat like a large
sponge. The "sponge" absorbs the acid without changing the pH much. The
"sponge's" capacity is limited however; once the buffering capacity is used
up, the pH changes more rapidly as acids are added.
Buffering has both positive and negative consequences. On the plus side, the
nitrogen cycle produces nitric acid (nitrate). Without buffering, your
pool's pH would drop over time (a bad thing). With sufficient buffering, the
pH stays stable (a good thing). On the negative side, hard water often
almost always has a large buffering capacity. If the pH of the water is too
high the buffering capacity makes it difficult to lower the pH to a more
appropriate value. Naive attempts to change the pH of the water usually fail
because the buffering effects are ignored.
How much buffering does your pool need? The proper alkalinity level for a
Fiberglass surface is 125 ppm to 150ppm.
Low total alkalinity waters make pH control difficult because of the lack of
buffering capacity (or poor resistance to ph change). Alkalinity must be
increased in these waters to offset the possibility of the water reverting
to acid.
Many waters are of high total alkalinity (buffering capacity) and high pH
levels. To get these waters into the swimming pool "comfort zone" it is
necessary to destroy a portion of the alkalinity so that the pH can be
lowered. This can be accomplished by the addition of muriatic acid.